Having clean escaped from one’s pursuers immediately (5,4)
I believe the answer is:
right away
'immediately' is the definition.
('right away' can be a synonym of 'immediately')
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for right away that I've seen before include "This very minute, without delay" , "in no time" , "This instant, without delay" , "without hesitation" , "Immediately" .)