He keeps attempting to name a German city (5)
I believe the answer is:
trier
'german city' is the definition.
(Trier is a city in Germany)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for trier that I've seen before include "German town, the capital of the northern empire in Roman times" , "town in Germany" , "One has a crack" , "Persevering type" , "One who doesn't give up - judge?" .)