Head of house, one sounding inquisitive (5)
I believe the answer is:
prior
'head of house' is the definition.
(I've seen this before)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for prior that I've seen before include "Preceding" , "More important" , "Source of poetry in 17th century" , "Former - churchman" , "head of a religious community" .)