Heart of policeman that might melt (3)
I believe the answer is:
ice
'that might melt' is the definition.
(ice might melt)
'heart of policeman' is the wordplay.
'heart of' indicates a hidden word.
'ICE' is hidden within 'policeman'.
(Other definitions for ice that I've seen before include "Diamond" , "Constituent of 2dn" , "such an age" , "Glaciate" , "Formality" .)