Hungry vampire, Dracula biting the vicar last of all (5)
I believe the answer is:
eager
'hungry' is the definition.
(I've seen this before)
'vampire dracula biting the vicar last of all' is the wordplay.
'last of all' indicates one should take the final letters.
The final letters of 'vampire dracula biting the vicar' are 'EAGER'.
(Other definitions for eager that I've seen before include "Longing to see" , "Sharp" , "Keen - enthusiastic" , "Enthusiastic, avid" , "Swiss mountain" .)