I censored articles about understandably stiff-looking Captain (7)
I believe the answer is:
scarlet
'i' is the definition.
Both the answer and definition are adjectives. Maybe there's an association between them I don't understand?
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for scarlet that I've seen before include "Miss O'Hara appearing briefly" , "Cartels (anag.)" , "Vivid red" , "immoral" , "Cherry-red" .)