I censored articles about understandably stiff-looking Captain (7)
I believe the answer is:
scarlet
'i' is the definition.
Both the definition and answer are adjectives. Perhaps you can see a link between them that I don't see?
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for scarlet that I've seen before include "Miss O'Hara appearing briefly" , "Cartels (anag.)" , "Vivid red" , "immoral" , "Cherry-red" .)