Intense ones face off by English river (9)
I believe the answer is:
tennessee
'river' is the definition.
(I know that Tennessee is a river)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for tennessee that I've seen before include "playwright's assumed first name" , "State of south-east US" , "Southern US state" , "16th US state" , "Name of US dramatist" .)