Italian Charlie provides stimulation (5)
I believe the answer is:
tonic
'stimulation' is the definition.
(thesaurus)
'italian charlie' is the wordplay.
'italian' becomes 'toni' (I can't justify this - if you can you should give a lot more credence to this answer).
'charlie' becomes 'C' (phonetic alphabet).
'toni'+'c'='TONIC'
'provides' is the link.
Can you help me to learn more?
(Other definitions for tonic that I've seen before include "Important note" , "Small drink of spirits" , "Restorative that invigorates" , "something providing a boost" , "A pick-me-up drink, nice with gin" .)