Jump the gun? (5)
I believe the answer is:
start
This clue is a double definition.
'jump' is the first definition.
('start' can be a synonym of 'jump')
'the gun?' is the second definition.
(thesaurus)
(Other definitions for start that I've seen before include "Begin with sudden movement of surprise" , "get under way" , "Begin - opening move" , "Jump suddenly" , "Set in motion" .)