Leaders with a fifty-fifty chance of falling on their faces? (5)
I believe the answer is:
heads
'leaders' is the definition.
(head is a kind of leader)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for heads that I've seen before include "Obverse result of coin-tossing" , "Goes for" , "Chiefs" , "Obverse of a coin" , "School principals" .)