Live with team on outskirts of Rome (6)
I believe the answer is:
reside
'live' is the definition.
(I know that reside is a more specific form of live)
'team on outskirts of rome' is the wordplay.
'team' becomes 'side' (both can mean a sports team).
'on' means one lot of letters go next to another.
'outskirts of' means to remove the middle letters (only letters on the outskirts).
'rome' with its centre taken out is 're'.
'side' put after 're' is 'RESIDE'.
'with' is the link.
(Other definitions for reside that I've seen before include "'Live, dwell (6)'" , "Live (at an address)" , "Occupy a place" , "Live (in a place)" , "Lodge" .)