Maybe, one anaesthetic? (6)
I believe the answer is:
number
I believe this clue is a double definition.
'maybe one' is the first definition.
(one is a number)
'anaesthetic?' is the second definition.
(i.e. something that makes things numb)
(Other definitions for number that I've seen before include "For example, one" , "Cardinal or ordinal" , "Part of musical" , "Count - a digit?" , "(Symbol for) quantity" .)