More courageous as a player? (5)
I believe the answer is:
gamer
This clue is a double definition.
'more courageous' is the first definition.
('game' can be similar in meaning to 'courageous')
'a player?' is the second definition.
(I've seen this before)
'as' acts as a link.
(Other definitions for gamer that I've seen before include "One having fun with computer" , "One role-playing on computer" , "I bet" , "player using computer" , "Keen computer player" .)