Most daring undergarments (7)
I believe the answer is:
bravest
'most daring' is the definition.
(I've seen this before)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for bravest that I've seen before include "Most heroic" , "Most valiant" , "Most courageous" , "Most handsome" , "Most daring" .)