Number of employees possibly quartered (5)
I believe the answer is:
staff
'number of employees' is the definition.
'staff' can be an answer for 'employees' (I've seen this in other clues). I am not certain of the 'number of' bit.
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for staff that I've seen before include "Employees; sign of office" , "Administrators etc - stick" , "Rod; workers" , "Walking-stick" , "See 11" .)