Peaty coal failed to start fire (6)
I believe the answer is:
ignite
'fire' is the definition.
(thesaurus)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for ignite that I've seen before include "Swan constellation" , "Combust" , "'Set alight, fire up (6)'" , "Put a match to" , "Spark off" .)