Pile of wood set on fire, watched from behind chain (8)
I believe the answer is:
pyrenees
'chain' is the definition.
(I know that Pyrenees is a chain)
'pile of wood set on fire watched from behind' is the wordplay.
'pile of wood set on fire' becomes 'pyre' (I can't explain this - if you can you should believe this answer much more).
'watched' becomes 'seen' (I've seen this before).
'from behind' is a reversal indicator.
'seen' written backwards gives 'nees'.
'pyre'+'nees'='PYRENEES'
Can you help me to learn more?
(Other definitions for pyrenees that I've seen before include "Mountains between France and Spain" , "Mountain range in southwest Europe" , "French/Spanish mountains" , "European mountains" , "Mountain chain between France and Spain" .)