Proverb used by head, a gentleman (5)
I believe the answer is:
adage
'proverb' is the definition.
('adage' can be a synonym of 'proverb')
'used by head a gentleman' is the wordplay.
'used by' says the answer is hidden in the clue.
'ADAGE' is hidden in the letters of 'head a gentleman'.
(Other definitions for adage that I've seen before include "Short statement expressing a general truth" , "Saying, saw" , "Axiom" , "Proverb expressing a general truth" , "Wise old saying" .)