Rattle, unnerve (7)
I believe the answer is:
fluster
I believe this clue is a double definition.
'rattle' is the first definition.
(thesaurus)
'unnerve' is the second definition.
(thesaurus)
(Other definitions for fluster that I've seen before include "Make hot and flurried." , "Ruffle" , "Agitate" , "Confuse" , "Disconcert" .)