Rebellious as well, ordered south (7)
I believe the answer is:
lawless
'rebellious' is the definition.
'as well ordered south' is the wordplay.
'ordered' indicates an anagram.
'south' becomes 's' (synonyms).
'as'+'well'='aswell'
'aswell' anagrammed gives 'lawles'.
'lawles'+'s'='LAWLESS'
(Other definitions for lawless that I've seen before include "disobedient" , "Without rules" , "Anarchic, without any controls" , "Slew Sal for being criminal" , "Wild wild" .)