Riddle deployed in game (6)
I believe the answer is:
enigma
'riddle' is the definition.
(I know that riddle can be written as enigma)
'deployed in game' is the wordplay.
'deployed' indicates anagramming the letters.
'in'+'game'='ingame'
'ingame' with letters rearranged gives 'ENIGMA'.
(Other definitions for enigma that I've seen before include "cryptic puzzle!" , "It's mysterious like gamine" , "WWII cipher" , "Elgar Variations nickname" , "Coding device" .)