Rise to be a toff (5)
I believe the answer is:
swell
I believe this clue is a double definition.
'rise' is the first definition.
(thesaurus)
'a toff' is the second definition.
(wealthy or high-class person)
'to be' is the link.
(Other definitions for swell that I've seen before include "part of organ" , "First class" , "Puff up" , "Expand - great!" , "Grow larger; excellent" .)