Rob him of character! (3)
I believe the answer is:
roy
'him of character' is the definition.
'Roy' can be an answer for 'him'. I'm not certain of the 'of character' bit.
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for roy that I've seen before include "Man" , "Rob . . . was a famous Scottish outlaw" , "-- Lichtenstein, US artist" , "- Orbison, US singer" , "-- Hattersley; -- Jenkins" .)