Rustic, pastoral (7)
I believe the answer is:
bucolic
This clue is a double definition.
'rustic' is the first definition.
(bucolic is a kind of rustic)
'pastoral' is the second definition.
(synonyms)
(Other definitions for bucolic that I've seen before include "Pastoral poem" , "Relating to rural life" , "Rustic - pastoral" , "Of rural or pastoral life" , "Agrarian" .)