Sailor, one leaving ship when capsized? (3)
I believe the answer is:
tar
'sailor' is the definition.
(slang term for a sailor)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for tar that I've seen before include "Black substance in cigarettes" , "Sailor (colloq.)" , "Black liquid from coal" , "Tobacco residue; sailor" , "Timber preservative" .)