Sinatra cryptically leading line of stars! (6)
I believe the answer is:
astral
'of stars' is the definition.
(relating to stars or astronomy)
'sinatra cryptically leading line' is the wordplay.
'sinatra cryptically' becomes 'astra' (I can't explain this - if you can you should give a lot more credence to this answer).
'leading' says to take the initial letters (the leading letter of the word).
The initial letter of 'line' is 'l'.
'astra'+'l'='ASTRAL'
Can you help me to learn more?
(Other definitions for astral that I've seen before include "Characteristic of stars" , "19 [STELLAR]" , "Starry sort of altars." , "like a star" , "Universal" .)