Sinner's foremost sin (5)
I believe the answer is:
stray
'sin' is the definition.
(I've seen this in another clue)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for stray that I've seen before include "Waif and - -" , "Lost pet" , "out of place" , "Go off course" , "Wander; be unfaithful" .)