Small diagram in collection (5)
I believe the answer is:
inset
'small diagram' is the definition.
'in collection' is the wordplay.
'collection' becomes 'set' (set is a kind of collection).
'in'+'set'='INSET'
(Other definitions for inset that I've seen before include "Thing inserted" , "Part of picture" , "Intimidated" , "Small picture inserted within a larger one" , "Piece let into a garment" .)