Snout stuck in pipe? (7)
I believe the answer is:
tobacco
'pipe?' is the definition.
(synonyms)
I don't understand how the remainder of the clue works.
(Other definitions for tobacco that I've seen before include "Leaves that are smoked" , "New World product" , "Addictive leaf" , "Put that in your pipe and smoke it!" , "Smokable plant" .)