Stimulant drug — what one’s on when poor, mostly (5)
I believe the answer is:
upper
'stimulant drug' is the definition.
(I know that upper is a type of stimulant drug)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for upper that I've seen before include "Amphetamine pill" , "Higher; superior" , "Higher in rank" , "Higher in status" , "Stimulant drug (informal)" .)