Strengthened control for horse used unnaturally (10)
I believe the answer is:
reinforced
'strengthened' is the definition.
(synonyms)
'control for horse used unnaturally' is the wordplay.
'control for horse' becomes 'rein' (I've seen this before).
'used unnaturally' becomes 'forced' (I can't explain this - if you can you should believe this answer much more).
'rein'+'forced'='REINFORCED'
Can you help me to learn more?
(Other definitions for reinforced that I've seen before include "Underlined" , "Added to" , "Sort of concrete" , "Strengthened" .)