Tasmanian would be one that I defame (8)
I believe the answer is:
islander
'tasmanian would be one' is the definition.
I can't tell whether this definition defines the answer.
'i defame' is the wordplay.
'defame' becomes 'slander' (synonyms).
'i'+'slander'='ISLANDER'
'that' is the link.
Can you help me to learn more?
(Other definitions for islander that I've seen before include "Rum person perhaps" , "Eg, a Manxman" , "Orcadian perhaps" , "Native of Bali, perhaps" , "E.g. Shetland inhabitant" .)