Thin core becoming small — it could shock you (5)
I believe the answer is:
taser
'it could shock you' is the definition.
(a Taser gives electric shocks)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for taser that I've seen before include "Police stun weapon" , "The weapon delivers a temporary paralysing electric shock" , "Weapon used to deliver a temporarily paralysing electric shock" , "Shocking device used by the police?" , "Device using electrified darts to stun" .)