Third man to arrive sounds competent (4)
I believe the answer is:
abel
'third man' is the definition.
(biblical third man after Adam and Cain)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for abel that I've seen before include "One of the first children" , "Slain biblical brother" , "Cain's younger brother" , "Bale out with murder victim" , "one killed early" .)