Thoughtful, solemn (7)
I believe the answer is:
serious
I believe this is a double definition.
'thoughtful' is the first definition.
(similar in meaning)
'solemn' is the second definition.
(similar in meaning)
(Other definitions for serious that I've seen before include "Important -- grave" , "Earnest - important" , "Important - solemn" , "Earnest; vital" , "Stern" .)