Titularly, John Wayne (4)
I believe the answer is:
duke
'john wayne' is the definition.
(I know that john wayne can be written as Duke)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for duke that I've seen before include "Highest ranked British peer" , "Lord" , "Member of the nobility" , "Nobleman of the highest rank" , "Highest ranking British peer" .)