Tribal chief's brain specialist?
I believe the answer is:
headman
'tribal chief's' is the definition.
(synonyms)
'brain specialist?' is the wordplay.
'brain' becomes 'head' (synonyms).
'specialist?' becomes 'man' (I can't justify this - if you can you should give a lot more credence to this answer).
'head'+'man'='HEADMAN'
Can you help me to learn more?
(Other definitions for headman that I've seen before include "Chieftain" , "Leader" , "Boss" , "Village chief" .)