Unnerved, shocked (6)
I believe the answer is:
shaken
This clue is a double definition.
'unnerved' is the first definition.
(thesaurus)
'shocked' is the second definition.
(I've seen this before)
(Other definitions for shaken that I've seen before include "Disturbed like cocktail?" , "not left undisturbed" , "Agitated or joggled" , "James Bond liked his martinis this way, not stirred" , "jarred" .)