Unprepared, I am quick with excuses, at heart (9)
I believe the answer is:
impromptu
'unprepared' is the definition.
(impromptu means improvised or unprepared)
'i am quick with excuses at heart' is the wordplay.
'i am' becomes 'I'm' (contraction).
'quick with' becomes 'prompt' (I can't explain this - if you can you should give a lot more credence to this answer).
'at heart' means to look at the middle letters.
The middle letter of 'excuses' is 'u'.
'im'+'prompt'+'u'='IMPROMPTU'
Can you help me to learn more?
(Other definitions for impromptu that I've seen before include "unrehearsed piece" , "Without much planning" , "Unplanned; composition" , "Extemporaneous speech" , "Unprepared" .)