Very cold beer (6)
I believe the answer is:
bitter
This clue is a double definition.
'very cold' is the first definition.
(bitter informally can mean very cold)
'beer' is the second definition.
(bitter is a type of beer)
(Other definitions for bitter that I've seen before include "Sour taste or resentful" , "English beer, sounds sour" , "Causing unhappiness" , "drink" , "Hard to accept" .)