What I wear on head is rubbish! (2,3)
I believe the answer is:
my hat
'is rubbish' is the definition.
(both are said to show you don't believe something)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for my hat that I've seen before include "I refuse to believe" , "nonsense" , "Old-fashioned exclamation" , "stuff!" , "Out of respect I might remove this" .)