Catches on small branches (5)
I believe the answer is:
twigs
This clue is a double definition.
'catches on' is the first definition.
('twig' can be a synonym of 'catch on')
'small branches' is the second definition.
(I've seen this before)
(Other definitions for twigs that I've seen before include "Kindling" , "Understands" , "Small branches" , "Catches on" , "Slender (tree) shoots" .)