Good deal of surprise on locating river (6)
I believe the answer is:
amazon
'river' is the definition.
(Amazon River is an example)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for amazon that I've seen before include "seller on the Internet" , "woman soldier" , "S. America's longest river" , "Female warrior of Greek myth" , "River in South America" .)