Officer playfully followed by Barbara (5)
I believe the answer is:
major
'officer' is the definition.
(type of military officer)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for major that I've seen before include "5,27 [PRIME MINISTER]" , "Significant, main" , "Of greater importance or stature" , "Important, significant" , "Commissioned military officer" .)