Relatively mature, or about to be led astray (5)
I believe the answer is:
older
'relatively mature' is the definition.
I can't judge whether this defines the answer.
'about to be led astray' is the wordplay.
'about' means one lot of letters goes inside another.
'to' becomes 'or' (I can't explain this - if you can you should believe this answer much more).
'astray' indicates an anagram.
'led' with letters rearranged gives 'lde'.
'or' enclosing 'lde' is 'OLDER'.
'or' is the link.
Can you help me to learn more?
(Other definitions for older that I've seen before include "More advanced in point of time" , "more history" , "Increasingly mature" , "Getting on" , "as we all will be tomorrow" .)