Tribe's unusual colour (6)
I believe the answer is:
bistre
'colour' is the definition.
(I know that bistre is a type of pigment)
'tribe's unusual' is the wordplay.
'unusual' is an anagram indicator.
'tribes' with letters rearranged gives 'BISTRE'.
(Other definitions for bistre that I've seen before include "Shade" , "Colour" , "brownish pigment" , "Tribes (anag) -- water-soluble brownish-yellow pigment" .)