Wonderful trio by Chopin, initially (5)
I believe the answer is:
magic
'wonderful' is the definition.
(I've seen this before)
'trio by chopin initially' is the wordplay.
'trio by' becomes 'magi' (I can't justify this - if you can you should believe this answer much more).
'initially' suggests taking the first letters.
The first letter of 'chopin' is 'c'.
'magi'+'c'='MAGIC'
Can you help me to learn more?
(Other definitions for magic that I've seen before include "Witchcraft" , "Necromancy" , "Enchantment" , "Art that supposedly invokes supernatural powers" , "Mysterious quality" .)