Liars gun misfires, only once (8)
I believe the answer is:
singular
'only once' is the definition.
I can't tell whether this definition defines the answer.
'liars gun misfires' is the wordplay.
'misfires' is an anagram indicator (I've seen 'misfiring' mean this (I've seen this in other clues)).
'liars'+'gun'='liarsgun'
'liarsgun' with letters rearranged gives 'SINGULAR'.
Can you help me to learn more?
(Other definitions for singular that I've seen before include "number" , "distinctive" , "Strange - unique" , "Unusual, maybe unique" , "Odd; unique" .)